The appearance of WPF DataGrid and its inner elements (example: Cell, Row, Header, Summary etc.) can be customized using various properties exposed and by editing the elements’ Style.
<Window.Resources>
<!--Table summary cell style-->
<Style TargetType="syncfusion:GridTableSummaryCell">
<Setter Property="Background" Value="Beige"/>
<Setter Property="Foreground" Value="Red" />
<Setter Property="FontSize" Value="16" />
<Setter Property="FontFamily" Value="Congenial Black"/>
<Setter Property="FontWeight" Value="Bold" />
</Style>
<Style TargetType="syncfusion:TableSummaryRowControl">
<Setter Property="Background" Value="Bisque"/>
<Setter Property="FontStyle" Value="Italic"/>
<Setter Property="Foreground" Value="Red"/>
</Style>
<!--Group summary cell style-->
<Style TargetType="syncfusion:GridGroupSummaryCell">
<Setter Property="Background" Value="Beige"/>
<Setter Property="FontWeight" Value="SemiBold"/>
<Setter Property="Foreground" Value="DarkBlue"/>
<Setter Property="FontStyle" Value="Oblique"/>
<Setter Property="FontFamily" Value="Congenial Black"/>
<Setter Property="FontSize" Value="14"/>
</Style>
<!--Group summary row style-->
<Style TargetType="syncfusion:GroupSummaryRowControl">
<Setter Property="Background" Value="Bisque"/>
</Style>
<!--Caption summary cell style-->
<Style TargetType="syncfusion:GridCaptionSummaryCell">
<Setter Property="Background" Value="Beige"/>
<Setter Property="FontWeight" Value="Bold"/>
<Setter Property="Foreground" Value="DarkBlue"/>
<Setter Property="FontStyle" Value="Italic"/>
<Setter Property="FontFamily" Value="Congenial Black"/>
<Setter Property="FontSize" Value="14"/>
</Style>
<Style TargetType="syncfusion:CaptionSummaryRowControl"
x:Key="captionSummaryRowStyle">
<Setter Property="Background" Value="Bisque"/>
</Style>
</Window.Resources>
Take a moment to peruse the WPF DataGrid - Styling documentation, to learn more about styles & templates code examples.